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31.
Anirban Biswas Debasree Deb Aloke Ghose Subhas Chandra Santra Debendra Nath Guha Mazumder 《Environmental monitoring and assessment》2014,186(7):4543-4551
Exposure to arsenic in arsenic endemic areas is most remarkable environmental health challenges. Although effects of arsenic contamination are well established, reports are unavailable on probable seasonal variation due to changes of food habit depending on winter and summer seasons, especially for endemic regions of Nadia district, West Bengal. Complete 24-h diets, drinking–cooking water, first morning voided urine samples, and diet history were analyzed on 25 volunteers in arsenic endemic Chakdah block of Nadia district, once in summer followed by once in winter from the same participants. Results depicted no seasonal variation of body weight and body mass index. Arsenic concentration of source drinking and cooking water decreased (p?=?0.04) from 26 μg L?1 in summer to 6 μg L?1 in winter season. We recorded a seasonal decrease of water intake in male (3.8 and 2.5 L day ?1) and female (2.6 and 1.2 L day?1) participants from summer to winter. Arsenic intake through drinking water decreased (p?=?0.04) in winter (29 μg day?1) than in summer (100 μg day?1), and urinary arsenic concentration decreased (p?=?0.018) in winter (41 μg L?1) than in summer (69 μg L?1). Dietary arsenic intake remained unchanged (p?=?0.24) over the seasons. Hence, we can infer that human health risk assessment from arsenic needs an insight over temporal scale. 相似文献
32.
Sharma KK Dubey JK Deka SC Chandrasekaran S Kalpana Gupta P Kumar A Vandana Devi MJ Singh B Baruah AA Kennedy JS Sharma ID Patyal SK Nath A 《Chemosphere》2007,68(4):790-796
Spiromesifen (Oberon) is a new insecticide and miticide of chemical class ketoenol active against white flies (Bemisia spp., Trialeuroides spp.) and spider mites (Tetranychus and Panonychus spp.). Due to its potential significance in insect resistance management, it is important to establish its behaviour on crop and environment. In the present study, the degradation/dissipation of spiromesifen on tea crop under tropical environmental conditions was studied and its DT(50) (t(1/2)), and DT(90) (time to reduce to 90% of the initial value) were estimated. Spiromesifen was sprayed on tea crop after first rain flush at four different locations @ 96 and 192ga.i.ha(-1). Samples of tea leaves were drawn at 0, 1, 3, 5, 7, 10, 15, 21 and 30 days after treatment and that of soil at 10 days after treatment and at harvest from 0 to 15 and 15 to 30cm layers. After crude extraction of tea leaves for spiromesifen residues with acetone:water, the contents were partitioned with cyclohexane:ethyl acetate and cleaned up on Florosil column. Soil residues were also extracted similarly. Quantification of residues was done on GC-MS in Selected Ion Monitoring (SIM) mode in mass range 271-274m/z. The LOQ of this method was found to be 0.05microgg(-1) while LOD being 0.015microgg(-1). The DT(50) of spiromesifen when applied at recommended doses in tea leaves was found to be 5.0-8.5 days. Ninety-nine percent degradation was found to occur within 33-57 days after application. In soil, no residues of spiromesifen were detectable 10 days after treatment. 相似文献
33.
34.
Nath K Saini S Sharma YK 《Journal of environmental biology / Academy of Environmental Biology, India》2005,26(2):197-204
Different dilution levels of tannery treated effluent and their corresponding concentration of chromium (Cr6+) were studied in a petridish culture experiment on seed germination and seedling growth in radish (Raphanus sativus L). The different concentrations of Cr6+ (2, 5 and 10 ppm) and treated tannery effluent (10, 25 and 50%) showed reduction in seedling growth and related enzymatic activities with increase in concentration of Cr6+ in treatments and effluent both. The low concentration of chromium (2 ppm) and effluent dilution (10%) showed significant growth reduction separately. At this concentration of chromium and effluent dilution chlorophyll content, amylase, catalase and protein contents remained unchanged while with increase in Cr6+ concentration (>2ppm) and effluent dilution (> 10%) in treatments showed growth inhibitory effects. 相似文献
35.
Bhaskar Nath 《Environment, Development and Sustainability》2008,10(4):471-486
Most environmental professionals and decision-makers, and certainly the public at large, hold the view that the integrity
of earth’s natural environment will be conserved for posterity and sustainable development achieved if all the nations rigorously
enforced their environmental and emission standards. It is argued in this paper that this view, sincerely held by many as
an “axiomatic truth,” is mistaken and misplaced. This is because as a biogeochemical entity the Earth has limited self-regenerative
capacity (SRC) to cope with anthropogenic pollution, and all kinds of environmental problems ensue when that limit is exceeded.
Indeed, mounting environmental problems now occurring on all fronts amply testify to the fact that the limit has already been
exceeded. They also provide necessary and sufficient proof that environmental and emission standards have been woefully inadequate
for protecting earth’s natural environment and life-support systems. It is argued that true global environmental sustainability
will be achieved, paving the way to true global sustainable development, if and only if global environmental and emission
standards are set so that global anthropogenic pollution does not exceed the limit of earth’s natural SRC to cope with such
pollution. These and related issues are discussed in this paper. A simple mathematical model using basic mathematics is also
presented to explain how the phenomenon of “positive feedback” works in some of the environmental problems to exacerbate environmental
degradation and progressively to erode nature’s SRC.
相似文献
Bhaskar NathEmail: |
36.
Kaustubha Mohanty Debabrata Das Manindra Nath Biswas 《Journal of environmental science and health. Part. B》2013,48(5):452-463
Arachis hypogaea hulls, an agricultural waste, were used to prepare activated carbon by chemical activation with zinc chloride under four different activation atmospheres. The most important parameter in chemical activation was found to be the chemical ratio (activating agent/precursor). Carbonization temperature and time are the other two important variables, which had significant effect on the pore structure of carbon. The maximum Brunquer-Emmett-Teller (BET) surface area and micropore volume of the activated carbon was found to be 418 m2/g and 0.28 cm3/g, respectively. The activated carbon developed shows substantial capability to adsorb phenol from aqueous solutions. The kinetic data were fitted to the models of intraparticle diffusion, pseudo-second-order, and Lagergren, and followed more closely the pseudo-second-order chemisorption model. The isotherm equilibrium data were well fitted by the Langmuir and Freundlich models. Solution pH has significant effect on adsorption and the maximum uptake of phenol was reported at pH 3.5. 相似文献
37.
Kaushik Nath Suresh Panchani M. S. Bhakhar Sandip Chatrola 《Environmental science and pollution research international》2013,20(6):4030-4045
Utilization of agrowaste materials for the production of activated carbon, as an excellent adsorbent with large surface area, is well established industrially, for dephenolation of wastewater. In the present work, dried pods of Prosopis cineraria—a novel and low-cost agrowaste material—were used to prepare activated carbons by zinc chloride activation. Batch adsorption experiments were carried out to study the effects of various physicochemical parameters such as initial phenol concentration, adsorbent dose, initial solution pH, and temperature. Pseudo-first-order second-order and diffusion kinetic models were used to identify the possible mechanisms of such adsorption process. The Langmuir and Freundlich equations were used to analyze the adsorption equilibrium. Maximum removal efficiency of 86 % was obtained with 25 mg?L?1 of initial phenol concentration. The favorable pH for maximum phenol adsorption was 4.0. Freundlich equation represented the adsorption equilibrium data more ideally than the Langmuir. The maximum adsorption capacity obtained was 78.32 mg?g?1 at a temperature of 30 °C and 25 mg?L?1 initial phenol concentration. The adsorption was spontaneous and endothermic. The pseudo-second-order model, an indication of chemisorption mechanism, fitted the experimental data better than the pseudo-first-order Lagergren model. Regeneration of spent activated carbon was carried out using Pseudomonas putida MTCC 2252 as the phenol-degrading microorganism. Maximum regeneration up to 57.5 % was recorded, when loaded phenol concentration was 25 mg?L?1. The data obtained in this study would be useful in designing and fabricating an efficient treatment plant for phenol-rich effluents. 相似文献
38.
Kirti Soni Sachchidanand Singh Tarannum Bano R.S. Tanwar Shambhu Nath B.C. Arya 《Atmospheric environment (Oxford, England : 1994)》2010,44(35):4355-4363
Simultaneous measurements of aerosol absorption and scattering coefficients for the PM2.5 aerosols particles were done at Delhi during April 2008–March 2009 to estimate the aerosol single scattering albedo (SSA) and the Angstrom absorption exponents at the surface. The annual average SSA at 0.55 μm was found to be 0.70 ± 0.07 with only slight variations during the four seasons, summer (0.63 ± 0.06), monsoon (0.69 ± 0.07), winter (0.74 ± 0.03) and spring (0.72 ± 0.04). However, large variations in average absorption and scattering coefficients were seen during these four seasons. The average absorption coefficients during summer, monsoon, winter and spring were found to be 62.47 ± 21.27, 50.95 ± 43.61, 189.65 ± 85.94 and 90.65 ± 33.06 Mm?1 respectively. The corresponding scattering coefficients were 110.46 ± 36.15, 95.34 ± 49.46, 565.59 ± 274.59 and 236.56 ± 96.25 Mm?1. The Angstrom absorption exponent (ασ(abs)) remained close to unity throughout the year averaging at 1.02 ± 0.08, 1.02 ± 0.10, 1.04 ± 0.11, and 1.03 ± 0.05 during summer, monsoon, winter and spring seasons respectively, strongly indicating that the absorption at Delhi aerosol is mainly due to the abundance of black carbon of fossil fuel origin. 相似文献
39.
Microbial regeneration of spent activated carbon dispersed with organic contaminants: mechanism, efficiency, and kinetic models 总被引:2,自引:0,他引:2
Background and purpose
Regeneration of spent activated carbon assumes paramount importance in view of its economic reuse during adsorptive removal of organic contaminants. Classical thermal, chemical, or electrochemical regeneration methods are constrained with several limitations. Microbial regeneration of spent activated carbon provides a synergic combination of adsorption and biodegradation.Methods
Microorganisms regenerate the surface of activated carbon using sorbed organic substrate as a source of food and energy. Aromatic hydrocarbons, particularly phenols, including their chlorinated derivatives and industrial waste water containing synthetic organic compounds and explosives-contaminated ground water are the major removal targets in adsorption?Cbioregeneration process. Popular mechanisms of bioregeneration include exoenzymatic hypothesis and biodegradation following desorption. Efficiency of bioregeneration can be quantified using direct determination of the substrate content on the adsorbent, the indirect measurement of substrate consumption by measuring the carbon dioxide production and the measurement of oxygen uptake. Modeling of bioregeneration involves the kinetics of adsorption/desorption and microbial growth followed by solute degradation. Some modeling aspects based on various simplifying assumptions for mass transport resistance, microbial kinetics and biofilm thickness, are briefly exposed.Results
Kinetic parameters from various representative bioregeneration models and their solution procedure are briefly summarized. The models would be useful in predicting the mass transfer driving forces, microbial growth, substrate degradation as well as the extent of bioregeneration.Conclusions
Intraparticle mass transfer resistance, incomplete regeneration, and microbial fouling are some of the problems needed to be addressed adequately. A detailed techno-economic evaluation is also required to assess the commercial aspects of bioregeneration. 相似文献40.
Atmadeep Mazumdar Krishna Nirmalya Sen Balendra Nath Lahiri 《International journal of occupational safety and ergonomics》2007,13(1):49-61
The Haddon matrix is a potential tool for recognizing hazards in any operating engineering system. This paper presents a case study of operational hazards at a large construction site. The fish bone structure helps to visualize and relate the chain of events, which led to the failure of the system. The two-tier Haddon matrix approach helps to analyze the problem and subsequently prescribes preventive steps. The cybernetic approach has been undertaken to establish the relationship among event variables and to identify the ones with most potential. Those event variables in this case study, based on the cybernetic concepts like control responsiveness and controllability salience, are (a) uncontrolled swing of sheet contributing to energy, (b) slippage of sheet from anchor, (c) restricted longitudinal and transverse swing or rotation about the suspension, (d) guilt or uncertainty of the crane driver, (e) safe working practices and environment. 相似文献